Figure 12 PL spectra of the as-synthesized ZnO:Al nanowires on a silicon substrate showing intensity versus energy. It is obvious that well-doped ZnO nanostructures have been obtained especially sample ZnO:Al 4 which was doped with 2.4 at.% Al. From the EDAX result, it is very well confirmed that Al was incorporated into the NSs. In fact, the NRs contained 0.05 at.% Al as can be known from the Figure 9b inset table. During the doping process, rather than of Zn atoms being substituted by Al atoms, we believe that oxygen vacancies Selleckchem NVP-BGJ398 (V o) and zinc interstitials (Zn i ) were formed as Al atoms combined with oxygen in ZnO. Indeed, it was a deviation from the conventional doping

mechanisms in which Al is thought to substitute Zn atoms. Our idea is well supported by the PL spectra in Figure 12 in which emissions peaks in visible range can be attributed to formation of oxygen vacancies and zinc interstitials which also agrees with reference [6]. Conclusions Dopant plays an important role on controlling the morphology of ZnO NWs. As evident from the result, Cisplatin cost it indicates that the optimum dopant concentration to be about 2.4 at.% where a ‘pencil-like’ hexagonal NSs were formed. We also obtained very interesting NSs at 1.2 at.% which appear pencil-like but having a tail. We assume 2.4 at.% to be an optimum dopant concentration necessary which resulted in the formation of defined hexagonal shaped pencil-like NSs.

Once again, we would like to stress on the proposed method to obtain Al-doped ZnO (ZnO:Al)

NSs. The intensity of UV emission increases with increase in doping which is observed on the PL spectra presented before. Especially, the UV emission is enhanced which is an indication of its practicality in optical sensing application. From SEM, FESEM, and PL images, we felt that the doping mechanism occurs via Sinomenine formation of oxygen vacancies (V o) and zinc interstitials (Zn i ) rather than substitution as is the case for conventional this website methods. Acknowledgements The authors thank the Department of Physics, Faculty of Science and Ibnu Sina Institute, Universiti Teknologi Malaysia, Johor, for all facilities provided as well as to Malaysian Government (GUP) under vote 08 J25 for funding the project. References 1. Cui Y, Zhong Z, Wang D, Wang WU, Lieber CM: High performance transistors. Nano Lett 2003,3(2):149–152.CrossRef 2. Lauhon LJ, Gudiksen MS, Lieber CM: Semiconductor nanowire heterostructures: philosophical transactions of the Royal Society of London, Series A: mathematical and physical science. Philos Trans R Soc Lond 2004, 362:1247–1260.CrossRef 3. Lee DJ, Kim HM, Kwon JY, Choi H, Kim SH, Kim KB: Structural and electrical properties of atomic layer deposited Al-doped ZnO films. Adv Funct Mater 2011, 21:448–455.CrossRef 4. Dang HY, Wang J, Fan SS: The synthesis of metal oxide nanowires by directly heating metal samples in appropriate oxygen atmospheres. Nanotechnology 2003, 14:738–741.